Vector Graphic
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01. Choose Scan
Choose a worthy scan you can vector. It's a waste of time if you use a clean scan. I used this Mai HiME scan with Mai and Natsuki (click of thumbnail).02. Outlines
There are many possibilities to start your vector. The easiest way is to make black outlines. But you can also make them colored, however, it's a little bit harder. No outlines can also look good. If you want to start like this, then skip the second step.
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Draw the outlines about 1px and be sure to make them very close to the scan. Tip: Hold it longer and strecht the pen and you can make nice round lines.
03. Shading and Highlights
Now you have the outlines in many layers. To merge them together just delete the scan and go to Layer -> Merge Visible. I suggest to save the outlines before the merging and save as a new file.You can make the shading and highlights similar to the scan or make your own colors. I'm doing my own shadings but for this tutorial I used the other technique, which is easier, too. If you're able to make your own shadings just start with the base colors.

04. Color
Go to the scan's layer again and start with the color below the shadows.


